CHEMISTRY 11 YEAR END REVIEW
A. SAFETY
and MEASUREMENT
1. Distinguish
between exact and measured quantities. Exact quantities are counting numbers or metric relationships
(unit analysis) that are known precisely with unlimited (i.e. infinite) sig.
figs. Measured quantities come from measurements and are subject to uncertainty
(need to express with sig. figs.).
2.
Simplify (2.55 x 103) (6.5
x 10-10) = 9.8 x 104
(1.7 x 10-11)
3. Given
that 2.2 lb. = 1.0 kg:
a)
convert 35 lb. to kg b)
convert 22 kg to lb. a)
15.9 kg b) 48.4 lb.
4. How
many significant figures are in each of the following measured quantities:
a) 0.0052 2 b)
35.02 4 c)
35.00 4 d)
5 x 103 1
5. Add
or subtract the following measured quantities (remember sig. fig. rules):
a) 25.02 - 3.511 b) 5.21 x 107 + 6.21 x 108 c) 25.22 d) 6.19 x 103 - 1.13 x 102
+3.336
a) 21.51 b)
6.73 x 108 c) 28.56 d) 6.08 x 103
6. Multiply
or divide the following measured quantities:
a) 25.35 x 32 b)
3.55 x 1022 x 4.1 x 1012 a) 8.1
x 102
b) 1.5 x 1035
7. A
25.5 g object has a volume of 35.5 mL. Calculate the density of the object. 0.718 g/mL
8. Ethanol
has a density of 0.789 g/mL.
a) What volume will 32.5 g occupy?
41.2 mL
b) What mass will a volume of 301.0 mL have? 237 g
B. ATOMIC
THEORY
1. Briefly describe the essential features the models of the atom developed by Dalton, Rutherford, Thomson and Bohr.
Dalton - homogeneous, indivisible sphere
Thomson
- mobile electrons are embedded in a positive mass.
Rutherford
- electrons orbit a dense, positively charged nucleus. The atom is mainly empty
space.
Bohr
- electrons are located in specific energy levels (shells)
2. Describe
the Law of Constant Composition and the Law of Conservation of Mass. Law of Constant Composition (also known
as Law of Definite Proportions) - a compound is formed from a simple whole
number ratio of elements
Law
of Conservation of Mass - mass can neither be created nor destroyed.
3. Which
of the above laws explains why you can balance reactions? Explain. Law of Conservation of Mass. Each atom
must be accounted for in the balancing process in order to ensure that this law
is not broken.
4. Which
of the above laws explains why water is always 2 parts H and 1 part O? Law of Constant Composition (Definite
Proportions)
5. Pick
one of the atomic theories in question #1 that first explained each of the
observations below:
a) The spectral lines in a hydrogen
discharge tube. ________________________________ Bohr
b) Atoms combine in simple whole number ratio to
form compounds. _________________ Dalton
c) Matter contains positive and negative
particles. _________________________________ Thomson
6. Draw
the Bohr (atomic) Diagram for F, Ca, K, Al, C and Br.
|
F |
Ca |
K |
Al |
C |
Br |
|
|
2 e- |
1 e- |
|
|
17 e- |
|
|
8 e- |
8 e- |
3 e- |
|
8 e- |
|
7 e- |
8 e- |
8 e- |
8 e- |
4 e- |
8 e- |
|
2 e- |
2 e- |
2 e- |
2 e- |
2 e- |
2 e- |
|
9 p+ |
20 p+ |
19 p+ |
13 p+ |
6 p+ |
35 p+ |
7. Draw
the Bohr (atomic) diagrams for F-, Al3+, P3- and
Mg2+.
|
F- |
Al3+ |
P3- |
Mg2+ |
|
|
|
8e- |
|
|
8e- |
8e- |
8e- |
8e- |
|
2e- |
2e- |
2e- |
2e- |
|
9 p+ |
9 p+ |
9 p+ |
9 p+ |
8. The
number of p+, n0 and e- in Na+ are:
__________, __________, __________.11p+, 12n0 and 10e-
9. An
element has 6 p+, 8 n0 and 6 e-. What is its
atomic mass? 14.00 amu
10. Complete
the following table:
|
|
p+ |
n0 |
e- |
Atomic
Number |
Atomic
Mass |
Charge |
|
C |
6p+ |
6n0 |
6e- |
6 |
12.00 amu |
0 |
|
14C |
6p+ |
8n0 |
6e- |
6 |
14.00 amu |
0 |
|
3H |
1p+ |
2n0 |
1e- |
1 |
3.00 amu |
0 |
|
20Ne |
10 |
10 |
10e- |
10 |
20.00 amu |
0 |
|
15N |
7p+ |
8n0 |
7e- |
7 |
15.00 amu |
0 |
11. Define
an isotope. An isotope is
one atom of an element. Most elements have more than one isotope. Each isotope
of an element has a different mass but behaves in the same way chemically. They
have different masses due to different numbers of neutrons but have the same
number of protons.
12. Calculate
the average atomic mass of magnesium given the following data:
24Mg 78.7% 25Mg 10.1% 26Mg 11.2% 24.33 amu
13. Distinguish
between a chemical family and a chemical period. Chemical family is a name given to a group in the
periodic table e.g. noble gases while a period is a row of the periodic table.
14. Describe
what happens to the atomic mass and number as you move to the right within a
period on the periodic table.
As you move to the right within a period on the periodic table the atomic
number increases as does the atomic mass.
15. State
three things that elements in the same chemical family have in common. Three
things that elements in the same chemical family have in common - similar
chemical reactivity, similar physical properties, and same outer (valence)
electron structure.
16. Circle
each reactive atom or ion.
a) Na
b) Na+
c) S
d) S2-
e) He The reactive species are: a) Na c)
S; we know this because atoms want to acquire a stable octet of
electrons, ions already have this … so atoms are more reactive!
17. Complete
the following chart.
|
|
p+ |
n0 |
e- |
No. of valence e- |
|
Li+ |
3p+ |
4n0 |
2e- |
1 e- |
|
Mg2+ |
12p+ |
12n0 |
10e- |
8 e- |
|
S |
16p+ |
16n0 |
16e- |
6 e- |
|
S2- |
16p+ |
16n0 |
18e- |
8 e- |
|
Ne |
10p+ |
10n0 |
10e- |
8 e- |
C. CHANGES
IN MATTER
1. Define
physical and chemical change.
Physical change is a change in the state of matter of a chemical (or appearance) while a chemical change involves
a change in the chemical structure (as a result of a chemical reaction which
involves a rearrangement of atoms).
2. Circle
each example of chemical change.
a) iron rusts b) silver tarnishes c) ham is sliced
d) water evaporates e) ice sublimes f) gasoline burns
g) salt dissolves h) steam condenses i) water is converted into H2
and O2
The
examples of chemical change are:
a) iron rusts b) silver tarnishes f) gasoline burns
i) water is converted into H2
and O2 . The rest are physical changes.
3. Define
exothermic and endothermic change. Exothermic change involves the giving off or release of energy
(usually heat) and endothermic changes involves the absorption of energy
(heat).
4. Describe
each a exothermic or endothermic.
a) 2 H2 + O2
à
2 H2O + 500J
exothermic
b) 200 J + 2 KClO3 (s) à
2 KCl + 3 O2 (g) endothermic
c) H2O (s) à H2O (g) endothermic
d) H2O (g) à H2O (l) exothermic
5. Define
the following changes in state:
evaporation, freezing, condensation, sublimation and melting. Evaporation:
change from liquid to gas
Freezing:
change from liquid to solid
Condensation:
change from gas to liquid
Sublimation:
change from solid to gas OR gas to solid
Melting:
change from solid to liquid
6. At
100˚C determine the phase
(solid, liquid or gas) for each of the following compounds:
a) m.p. 20˚C b.p. 120˚C
liquid
b) m.p. 105˚C solid c) b.p. 25˚C gas
7. Define
element, compound and mixture.
Element: matter made up of only one kind of atom
Compound:
matter made up of two or more kinds of atoms. Mixture: matter composed of two
or more different chemicals
8. Describe
each as an element, compound or mixture.
a) A
homogeneous brown substance has a constant composition. After heating in a
vacuum it gives off a gas and leaves a silver liquid. compound
b) A
homogeneous purple solid has a constant composition. After heating the solid in
a vacuum it evaporates and re-condenses upon cooling. The molten solid does not decompose when an electrical
current is passed through it.
element
c) A
liquid has a boiling point of 105˚C. After boiling the liquid for 10
minutes, the boiling point changes to 110˚C. mixture
9.
Define
metals and nonmetals. Metals
- a chemical element found on the left side of the periodic table. All are
solid (except Hg), silver (except (Au and Cu), conduct electricity, shiney,
form positive ions (cations). Nonmetals – a chemical element found
on the right side of the periodic table. Can be solid, liquid or gas; can be
colored or colorless, generally don’t conduct electricity, dull, form
negative ions (anions).
10. Describe
how you could separate a mixture of sand and water. Filter it.
11. Describe how you would separate a mixture of ethanol and water by distillation. Draw a labeled diagram of the apparatus used. In your explanation include the boiling points of water and ethanol and the terms: distillation flask, condensation tube and collecting flask. Distillation uses the differences in boiling point to separate two different chemicals (one boils at a lower temp than the other). The boiling point of water is 100˚C and ethanol is 78.5˚C, therefore ethanol will boil first and be collected in the collecting vessel after being condensed back into a liquid in the condenser. See page 28 in Heath Chemistry for the diagram.
D. CHEMICAL
COMPOUNDS
1. Circle
each ionic compound.
a) NaBr b) KOH
c) HCl
d) NH4C1 e) CH4
f) NH3
The
ionic compounds are: a) NaBr b) KOH
d) NH4C1
2. Write
correct ionic formula for each combination.
a)
Mg ;
C1 b) NH4 ; O
c) Fe ; S d) A1 ; SO4
a) MgC12 b) (NH4)2O
c) Fe2S3 d) A12(SO4)3
3. Name each compound in the above question.
a)
magnesium chloride b)
ammonium oxide c) iron (III)
sulphide d) aluminum sulphate
4. Define
and give an example of a cation and anion.
Cation
(any positive ion) : Mg2+ Anion (any negative ion): Cl-
5. Circle
each cation.
a) K+
b) C1-
c) NaBr d) NH4OH
a) K+ c) Na+ d) NH4+
6. Circle
the formulas that have formula units.
a) CCl4
b) H20 c) C12
d) NaF e) NH4Br
d) NaF
e) NH4Br
7. Circle
the compounds that conduct electricity.
a) Na (s) b) NaCl (s) c) NaCl (aq) d) NaCl (l)
e) CCl4 (l) f) H2O (l) g) CH3OH (aq) h) NH4OH (aq)
a) Na (s) (all metals conduct) c) NaCl (aq) (aqueous ionic
compounds conduct)
d) NaCl (l) (all molten or melted ionic substances)
h) NH4OH (aq) (aqueous ionic compound)
8. Write
dissociation equations for:
a) Na2CO3 b) Fe2(SO4)3
a) Na2CO3 (s) à 2 Na+ (aq) + CO32- (aq)
b) Fe2(SO4)3
(s) à 2 Fe3+ (aq) + 3 SO42- (aq)
9. Draw
Lewis structures for:
a) CCl4 b) H2 c) CO2 d)
C2H2
a) CCl4 b) H2 c) CO2 d)
C2H2
10. Arrange
the compounds into the four categories: ionic, acids, or molecular
Na2SO4 H2SO4 CCl4 C2H6 KOH NH4OH CH3COOH NH4C1
Ionics: Na2SO4 NH4C1 KOH NH4OH
Acids: H2SO4 CH3COOH
Molecular:
C2H6 CCl4
11. Explain
why NaCl and CCl4
are stable compounds.
NaCl
and CCl4 are
stable compounds because each element has a filled valence shell and does not
want to lose or gain electrons or even share electrons with any other
atoms. This makes them unreactive.
12. Circle
the molecular compounds.
a) H2O b) HCl c) NaBr d)
NH4OH
a) H2O b)
HCl
13. Name
each binary molecular compound.
a) CCl4 b) CO2 c) P2O5 d)
SiCl
a) carbon tetrachloride b) carbon dioxide c) diphosphorus pentaoxide d) silicon monochloride
E. REACTIONS
1. Complete,
balance, and identify each reaction type. Write NR for those reactions that do
not occur (use
Activity
Series to determine this - only for SR reactions). All phases must be included!
a) C6H14 + O2 à
CO2 + H2O
a) 2 C6H14 (g) + 19
O2 (g) à 12 CO2 (g) + 14 H2O (g) hydrocarbon
combustion
b) Al2(SO4)3 + AgNO3 à
b) Al2(SO4)3
(aq) + 6 AgNO3 (aq) à 2 Al(NO3)3 (aq) + 3 Ag2SO4 (aq) double
replacement
c) NaCl + KOH à
c) NaCl (aq) + KOH (aq) à NaOH (aq)
+ KCl (aq) double
replacement
d) Au + Cu(NO3)2 à
d) Au (s) + Cu(NO3)2
(aq) à NR single
replacement
e) Cu + Au(NO3)3 à
e) Cu (s) + Au(NO3)3
(aq) à Cu(NO3)2 + Au (s) single
replacement
f) H2SO4 + NaOH à
f)
H2SO4 (aq) + NaOH
(aq) à Na2SO4 (aq) + 2 H2O
(l) double
replacement
g)
HgO à
g) HgO
(s) à Hg (l) + O2 (g) decomposition
h) Ca + H2O à
h) Ca (s) + 2 H2O (l) à Ca(OH)2 (s) + H2 (g) single
replacement
i) Al + I2 à
i) 2 Al (s) + 3 I2 (s) à 2 AlI3 synthesis
2. Write
a balanced chemical equation to show how solid iron reacts with oxygen from the
air to produce solid iron (III) oxide. Include all phase symbols. 2 Fe (s) + 3 O2 (g) à Fe2O3 (s)
3. Write
a normal double replacement for Cu(NO3)2 (aq) + NaOH (aq). Write the total
ionic and net ionic equations for this reaction.
Cu(NO3)2
(aq) + 2 NaOH (aq) à
Cu(OH)2 (aq)
+ 2 NaNO3
(aq)
Cu2+
(aq) + 2 NO3- (aq) + 2 Na+ (aq) + 2 OH- (aq) à Cu(OH)2 (s)
+ 2 Na+
(aq)+ 2 NO3-
(aq)
Cu2+
(aq) + 2 OH- (aq) à Cu(OH)2 (s)
F. MOLE
CONCEPT
1. State
Avogadro’s number and hypothesis. Avogadro’s number is 6.02 x 1023
2. Define
molar mass. Molar mass is
the mass of one mole of a chemical.
3. If
3.50 moles of an element has a mass of 14.0 g, calculate its atomic molar mass.
What is the element? 4.00 g/mol.
The element is He
4. Calculate
the number of moles in 50.0 L of H2 (g). 2.23 mol of H2 (g)
5. Calculate
the number of grams in 35.2 moles of cobalt. 2.074 x 103 g
6. Calculate
the number of atoms in 6.25 moles of copper atoms. 3.76 x 1024 atoms
7. Calculate
the number of moles of water molecules that is equal to 7.55 x 1022
molecules of water. 0.125
moles of water.
8. Calculate
the number of formula units of NaCl in 5.60 g of NaCl. 0.0958 moles or 5.77 x 1022 formula
units.
9. Calculate
the mass of 2.65 x 1027 atoms of iron. 2.46 x 105 grams of iron.
10. Calculate
the percent composition of each element in C2H6O. C = 52.13% H = 13.15% O =
24.72%
11. A
compound is 32.38% Na, 22.58% S and 45.07% O. Calculate the empirical formula
of the substance.
Check
your formula with the table of radicals. Na2SO4
12. What
is the empirical formula of C6H6? CH
13. A
molecular compound has an empirical formula of CH2 and a molecular
mass of 84 g/mol. Determine the molecular formula. C6H12
14. How
many moles of H2 gas at STP are in 100.0 L? 4.464 moles of H2 gas at STP
are in 100.0 L
15. How
many litres of NH3 gas at STP are in 2.5 moles? 56 L of NH3 gas
G. BONDING
1. Draw
an ionic crystal lattice for NaCl.
2. Explain
how two atoms bond ionically. Explain how two atoms bond covalently. Illustrate
your answers with examples.
3. What
does electronegativity refer to? Electronegativity is a relative number that expresses an atoms
desire for electrons. The higher the number the greater the desire. (Useful to
determine the polarity of bonds)
4. Find
the electronegativity of the following atoms from your periodic table: Na, F,
Br, S, O, Ca, Fr, Cu. Na =
0.9, F= 4.0, Br = 2.8, S= 2.5,
O=3.5, Ca = 1.0, Fr = 0.7, Cu = 1.9
5. Draw
the Lewis and structural diagrams of the following molecules. State their
shape. Determine whether they are polar or not.
a) Cl2 b) C2Cl2 c) PH3 d) HCN
e) CCl4 f) H2O g) CH3OH h) N2H4
a) C2H4 b) C2H5Cl
a) Cl2 b) C2Cl2 c) PH3 d) HCN
linear linear trigonal
pyramidal linear
e) CCl4 f) H2O g) CH3OH h) N2H4
tetrahedral angular tetrahedral
(around C) trigonal pyramidal
angular
(around O)
i) C2H4 j) C2H5Cl
trigonal planar tetrahedral
6. Describe
the three kinds of intermolecular forces and provide drawings to illustrate. London Dispersion Forces - found
between all molecules. It is the force of attraction of one molecules protons
and other molecules electrons. The greater the number of electrons the greater
the LDFs
Dipole-Dipole
Forces - the force of
attraction between the charges ends of molecules that are polar (positive ends
of one molecule attracted to the negative end of another). Only found with
polar molecules.
Hydrogen
Bonding - the very strong polar interaction between molecules that are
highly polar. Must have one of the following covalent bonds in the molecule:
O-H, N-H, F-H.
7. What
does the term isoelectronic mean? Isoelectronic means the same number of electrons. Used
in compare the intermolecular forces between two chemicals OR to describe the
stability of electron structures of ions (ions are isoelectronic with nearest
noble gases).
8. Explain
why CH4 has a much lower boiling point than H2O (they are
isoelectronic chemicals!) CH4
has a much lower boiling point than H2O since it is subject to only
London Dispersion forces while there are other intermolecular forces between
the water molecules. Since these chemicals are isoelectronic they have the same
relative amount of LDF but the polarity of the water molecule with its O-H bond
gives it hydrogen bonding as well
as dipole-dipole forces. Water has therefore, three intermolecular forces to
methane’s one.
H. PERIODIC
TABLE
1. Draw
an outline of the periodic table and indicate where each chemical family is
located. State where the
metals
and nonmetals are located. Describe the trends of ionization energy and atomic
radius.
2. State
what is meant by ionization energy and provide an equation to show the
ionization of Ca atoms. Ionization
energy is the energy required to cause a neutral atom to become a positive ion
(or the energy required to make the atom lose one electron and become a
positive ion).
Ca
(g) à Ca+ (g) +
1 e-
3. Which
is larger metal atoms or metal ions. Explain. Metal atoms are larger than metal ions because metal
ions have lost electrons and, as a result, no longer have the original valence
shell that the electrons were located in.
4. Which
is larger nonmetal atoms or nonmetal ions. Explain. Nonmetal ions are larger than nonmetal
atoms because these ions have gained electrons to fill up their valence shells.
The extra electrons force electrons that exist in the valence shell to move
outward a little to minimize electron-electron repulsions.
5. In
which chemical family is each element located? Cl, K, U, Ca, Xe, Fe, Ru, Lw Cl = halogen, K = alkali metal, U =
actinide series, Ca = alkaline earth, Xe = noble gas, Fe = transition element,
Ru = transition element, Lw = actinide series
6.
State the
periodic law.The Periodic
Law states that if the elements are arranged in order of increasing atomic
mass, a pattern can be seen in which the properties reoccur on a regular basis.
I. STOICHIOMETRY
1. How
many chlorine atoms are in 5 formula units of MgCl2? 10 Cl atoms
2. How
many moles of Br are in 10.0 moles of AlBr3? 30.0 moles
3. Given
the reaction: 2 H2 + O2 à 2 H2O How many moles of H2O
are produced by a) 5 moles O2 and b) 5.0 g O2 ? a) 10 moles H2O b) 0.63 moles H2O
4. If
the actual yield is 50.0 g and the theoretical yield is 70.0 g, what is the
percentage yield? 71.4%
5. Given: 2 Fe2O3 + 3 C à
4 Fe + 3 CO2. If 50.0 g of Fe2O3
completely reacts with excess carbon, how
many grams of carbon dioxide are produced? 20.7 g of CO2
6. C3H8
(g) + 5 O2
(g) à
3 CO2 (g)
+ 4 H2O (g). If 205g of C3H8 (g)
reacts with excess O2 (g), calculate the theoretical yield of CO2
(g). If the actual yield of CO2 was 500.0 g, calculate the
percentage yield. 614 g of
CO2 (g). The percentage yield would be 81.4%.
7. 2
H2 (g) + O2 (g)
à
2 H2O (l)
How
many grams of H2O are produced when 50.0 L of H2 (g) at
STP reacts completely to form water. 40.2 g
8.
2 NaCl à 2 Na + Cl2. How many litres of
Cl2 (g) are produced at STP when 100.0 g of NaCl completely react. 19.16 L of Cl2 (g)
9. 2
H2 (g) + O2 (g)
à
2 H2O (l)
If
8 moles of H2 (g) reacts with 3 moles O2 (g), determine
the amount (moles) of H2O (l) produced, the limiting
reactant and the amount of excess reactant. Mole of H2O (l) produced 6 moles. The
limiting reactant is O2 (g).The amount of excess reactant is 2
moles.
J. SOLUTION
CHEMISTRY
1. Pick
the compounds that would be soluble in CCl4.
a) NaCl b) CBr4 c) C2H2
d) HF e) H2O
b) CBr4 c) C2H2 d) HF (Rule is “like dissolves like” which means that
polar liquids will dissolve polar chemicals while nonpolar will dissolve
nonpolar).
2. Calculate
the number of grams NaCl required to prepare 100.0 mL of a 0.200 M solution. 1.17 grams NaCl
3. Calculate
the number of litres of NaCl required to obtain 0.50 g if the solution is 0.20
M. 0.043 L
4. How
many moles NaCl are in a 0.20 L of a 0.50 M solution. 0.10 moles
5.
25.0 moles NaOH is dissolved in 50.0 L of H2O. What is the
molarity? 0.500 M
6.
If 25.0 g NaOH is dissolved in 5.0 L of H2O, what is the
concentration? 0.125 M
7. If
25.0 mL of a 6.0 M NaOH solution is diluted to 100.0 mL, what is the new
molarity? 1.5 M
8. You
are given the equation H2SO4 + 2 NaOH à Na2SO4 + 2 H2O and that 50.0 mL of 0.20M
NaOH is required to neutralize 25.00 mL H2SO4. What is
the acid concentration?
0.20 M
K. ORGANIC
CHEMISTRY
1. Name
each organic structure
a) |
| | |
- C
- C -
C - C
-
| | | |
- C - methylbutane
(the 2 is not needed)
|
b)
|
| | | |
|
- C - C - C
- C -
C - C
- |
|
| | | |
- C
- 3-ethylhexane
|
- C -
|
c)
| |
| |
|
-
C - C
- C -
C - C
-
| | | |
|
- C- - C - 3-methyl-2-ethylpentane
|
|
- C -
|
d)
Cl
|
| | |
- C
- C -
C - C
-
| | | |
Br Cl 1-bromo-2,2-dichlorobutane
e) | |
| |
-
C - C -
C - C
-
|
| | |
- C - F 1-fluoro-3-methylbutane
|
f)
| | |
|
- C - C
- C -
C -
| | |
|
- C - 3-methylpentane
|
- C -
|
g) | |
| | | |
- C
- C -
C - C
- C -
C -
| | | | | |
- C
-
- C - 2-methyl-4-ethylhexane
|
|
- C -
|
h)
|
- C -
|
| | | | |
|
- C
- C -
C - C
- C -
C - C
-
| | | |
| | |
- C
-
Cl Br Br 1,3-dibromo-4-chloro-5-methyloctane
|
2. Draw
the structural formula for each organic chemical.
a)
1,1-dibromopentane
b)
3,3,4 - trimethylhexane
c)
4-ethyl-5-methyldecane
d)
2-hexene
e)
4-octyne
f)
cyclohexane
g)
2-methyl-4-chloro-3-octene
Cl
| | |
| | | |
|
- C
- C -
C = C - C
- C -
C - C -
| |
| | | |
- C -
3. Draw
all of the isomers of C5H12.